Sharp AR-M236 (serv.man12) User Manual / Operation Manual ▷ View online
MATERIAL SAFETY DATA SHEET
Data Revised: Jul. 31. 2002
Data Issued:
Data Issued:
Apr. 2. 2001
MSDS No. F-00981
83
Exposure limit values
OSHA-PEL (USA)
: 15mg/m
3
(Total Dust) , 5mg/m
3
(Respirable Dust)
ACGIH-TLV (USA)
: 10mg/m
3
(Total Dust) , 3mg/m
3
(Respirable Dust)
Personal Protective Equipment
Respiratory Protection
: Not required under intended use.
Hand Protection
: Not required under intended use.
Eye Protection
: Not required under intended use.
Skin Protection
: Not required under intended use.
Other Protective Equipment
: Use of a dust mask and goggles are recommended when handling a large
quantity of toner or during long term exposure, as with any non-toxic dust.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State:Solid
Form: Powder
Color:Black
Odor:odorless
Ph
: Not applicable
Boiling/Melting Point
: Not applicable
Softening Point (°C)
: 100 - 130
Flash Point (°C )
: Not applicable
Ignition Point (°C )
: > 350
Explosion Properties
: No data
Density (g/cm
3
)
: 1.1 (bulk density : 0.35)
Solubility in water
: Negligible
10. STABILITY AND REACTIVITY
Stability
: Stable
Hazardous Reactions
: Dust explosion, like most finely divided organic powders.
Conditions to Avoid
: Electric discharge, throwing into fire.
Materials to Avoid
: Oxidizing Materials
Hazardous Decomposition Products : CO, CO
2
and NO
X
Further Information
: None
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion (oral)
: LD
50
> 2000mg/kg (Rats)
Inhalation
: LC
50
> 4.97mg/L
Eye irritation
: Not an irritant (Rabbits)
Skin irritation
: Not an irritant (Rabbits)
Skin sensitizer
: No sensitization
Mutagenicity
: Negative (Ames Test)
Carcinogenicity
: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human
carcinogen). This classification is given to chemicals for which there is inadequate
human evidence, but sufficient animal evidence on which to base an opinion of
carcinogenicity. The classification is based upon the development of lung tumors in rats
receiving chronic inhalation exposures to free carbon black at levels that induce particle
overload of the lung. Studies performed in animal models other than rats did not show
any association between carbon black and lung tumors. Moreover, a two-year cancer
bioassay using a typical toner preparation containing carbon black demonstrated no
association between toner exposure and tumor development in rats.
human evidence, but sufficient animal evidence on which to base an opinion of
carcinogenicity. The classification is based upon the development of lung tumors in rats
receiving chronic inhalation exposures to free carbon black at levels that induce particle
overload of the lung. Studies performed in animal models other than rats did not show
any association between carbon black and lung tumors. Moreover, a two-year cancer
bioassay using a typical toner preparation containing carbon black demonstrated no
association between toner exposure and tumor development in rats.
Page: 3/4
MATERIAL SAFETY DATA SHEET
Data Revised: Jul. 31. 2002
Data Issued:
Data Issued:
Apr. 2. 2001
MSDS No. F-00981
84
Chronic Effect
: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate
degree of lung fibrosis was observed in 92% of the rats in the high concentration
(16mg/m
(16mg/m
3
) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of
the animals in the middle (4mg/m
3
) exposure group, but no pulmonary change was
reported in the lowest (1mg/m
3
) exposure group, the most relevant level to potential
human exposures.
12. ECOLOGICAL INFORMATION
No data are available.
13. DISPOSAL CONSIDERATIONS
Waste from Residues
: Waste material may be dumped or incinerated under conditions which meet all
federal, state and local environmental regulations.
Contaminated Packaging : Waste may be disposed or incinerated under conditions which meet all federal,
state and local environmental regulations.
14. TRANSPORT INFORMATION
UN Classification
: None
Not classified as hazardous for transport.
15. REGULATORY INFORMATION
US Information
TSCA (Toxic Substances Control Act):
All chemical substances in this product comply with all applicable rules or order under TSCA.
SARA (Superfund Amendments and Reauthorization Act) Title III
302 Extreme Hazardous Substance : None
311/312 Hazard Classification
311/312 Hazard Classification
: None
EU Information
1999/45/EC and 67/548/EEC
Symbol & Indication
: Not required
R-Phrase
: Not required
76/769/EEC
: All chemical substances in this product comply with all applicable rules
or order under 76/769/EEC.
16. OTHER INFORMATION
NFPA Rating (USA)
: Health=1 Flammability=1 Reactivity=0
WHMIS Legislation (Canada)
: This product is not a controlled product.
List of R phrases
: R11 : Highly flammable
References
IARC (1996) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.
65, Printing Process And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon,
pp.149-261
pp.149-261
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow,
U.Mohr, S.Takenaka, and R.Mermelstein (1991) Pulmonary Response to Toner upon Chronic Inhalation
Exposure in Rats.
Fundamental and Applied Toxicology 17, pp.280-299.
U.Mohr, S.Takenaka, and R.Mermelstein (1991) Pulmonary Response to Toner upon Chronic Inhalation
Exposure in Rats.
Fundamental and Applied Toxicology 17, pp.280-299.
The information on this data sheet represents our current data and best opinion as to the proper use in handling
of this product under normal conditions. However, all materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we do not guarantee that these are the only
hazards which exist.
of this product under normal conditions. However, all materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we do not guarantee that these are the only
hazards which exist.
Page: 4/4
MATERIAL SAFETY DATA SHEET
Data Issued:
Aug. 1. 2003
MSDS No. F-31201
85
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
: AR-271ND / AR-271DV / AR-271SD / AR-271SD-C (Black Developer)
Supplier Identification : Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance[ ] Preparation[X]
Area
(Country)
(Name and Telephone Number)
North
America
U.S.A.
Sharp Electronics Corporation
Sharp Plaza, Mahwah, NJ
Telephone number for information
Telephone number for information
: 1-800-237-4277
Emergency telephone number
: 1-800-255-3924
Canada
Sharp Electronics of Canada Ltd.
Telephone number for information
: 905-890-2100
Emergency telephone number
: 1-800-255-3924
Oceania
Australia
Sharp Corporation of Australia PTY. Ltd.
No1 Huntingwood Drive Huntingwood Blacktown N.S.W.
Telephone number for information
Telephone number for information
: 1300-13-50-22
Europe
Germany
Sharp Electronics (Europe) GMBH
Sonninstrasse 3, 20097 Hamburg
Telephone number to access MSDS
Telephone number to access MSDS
: 040-2376-2185
For more information
: 040-2376-2613
United
Kingdom
Sharp Electronics (U. K.) Ltd.
Telephone number for information
: 08705-274-277
France
Sharp Electronics France S.A.
Telephone number for information
: 01-49-90-34-00
Austria
Sharp Electronics GMBH
Telephone number for information
: 01-727-19-0
Italy
Sharp Electronics (Italy) S.P.A.
Telephone number for information
: 02895951
Spain
Sharp Electronics (Espana) S.A.
Telephone number for information
: 93-581-97-00
Netherlands Sharp Electronics Benelux B.V.
Telephone number for information
: 30-6359500
Sweden
Sharp Electronics Nordic AB
Telephone number for information
: 08-634-36-00
Switzerland
Sharp Electronics (Schweiz) AG
Telephone number for information
: 01-846-6111
Middle
East
U.A.E.
Sharp Middle East FZE
P.O.Box 17115 Jebel Ali, Dubai
Telephone number for information
Telephone number for information
: 04-815311
Ingredient
CAS No.
Proportion
OSHA PEL
ACGIH TLV
MAK-TWA
NOHSC-TWA
Iron powder
7439-89-6
> 90%
Not listed
Not listed
Not listed
Not listed
Styrene-Acrylate
copolymer
copolymer
29497-14-1
5-10%
Not listed
Not listed
Not listed
Not listed
Carbon black
1333-86-4
< 1%
3.5mg/m
3
3.5mg/m
3
Not listed
3mg/m
3
Page: 1/4
MATERIAL SAFETY DATA SHEET
Data Issued:
Aug. 1. 2003
MSDS No. F-31201
86
3. HAZARDS IDENTIFICATION
Most Important Hazards and Effects of the Products
Human Health Effects : There are no anticipated carcinogenic effects from exposure based on animal tests
performed using toner. When used as intended according to instructions, studies do
not indicate any symptoms of fibrosis will occur.
not indicate any symptoms of fibrosis will occur.
Environmental Effects : No data are available.
Specific Hazards
: Dust explosion (like most finely divided organic powders)
Directive 1999/45/EC(Europe): Not classified as dangerous
4. FIRST-AID MEASURES
Route(s) of Entry : Inhalation?
Skin?
Ingestion?
No
No
Possible but very unusual.
Inhalation
: Remove to fresh air. If symptoms occur, consult medical personnel.
Skin Contact : Wash with soap and water for 15 minutes or until particle is removed.
If irritation does occur, consult medical personnel.
Eye Contact : Flush eyes immediately with water for 15 minutes. If irritation does occur, consult medical
personnel.
Ingestion
: Rinse with water and drink several glasses of water . If irritation or discomfort does occur, consult
medical personnel.
5. FIRE –FIGHTING MEASURES
Extinguishing Media
: Water, CO
2
, foam and dry chemicals
Special Fire fighting Procedures : None
Fire and Explosion Hazards
Fire and Explosion Hazards
: Toner material, like most finely divided organic powders, may form an
explosive mixture.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
: None
Environmental Precautions
: None
Methods for Cleaning Up
: Wipe off with paper or cloth. Do not use vacuum cleaner when a large
amount is released. It, like most finely divided organic powders, is capable of
creating a dust explosion.
creating a dust explosion.
7. HANDLING AND STORAGE
Handling
Technical Measures
: None
Precautions
: None
Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or during
long term exposure, as with any non-toxic dust. Try not to disperse the particles.
Storage
Technical Measures
: None
Storage Conditions
: Keep container closed and Store in a cool and dry place.
Keep out of the reach of children.
Incompatible Products: None
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures
Ventilation
: Not required under intended use.
Page: 2/4
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