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DG

B

Date Revised : Aug.7, 2001

Date Issued : Jun.1, 1998

MSDS No. F-00831

  :   AL-100TD / DM-150TD / AL-110TD / AL-110DC (Black Toner)

 : Sharp Corporation
     22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

    Local suppliers are listed below.  Please contact the nearest supplier for additional information.

(Country)

(Name  and  Telephone  Number)

U.S.A.

Sharp Electronics Corporation
Telephone number for information :1-800-237-4277
Emergency telephone number

:1-800-255-3924

Canada

Sharp Electronics of Canada Ltd.
Telephone number for information : 905-890-2100
Emergency telephone number

:1-800-255-3924

United

Sharp Electronics (U.K.) Ltd.

Kingdom

Telephone number for information : 01922-474013

Australia

Sharp Corporation of Australia PTY. Ltd.
Telephone number for information : 1300-12-50-22

Germany

Sharp Electronics (Europe) GMBH
Telephone number for information : 40-2376-2737

Substance [ ]

Preparation [ X ]

Styrene-Acrylate 29497-13-1

 35-45%

Not listed

Not listed

Not listed

Not listed

copolymer
Styrene-

9002-52-6

35-45%

Not listed

Not listed

Not listed

Not listed

homopolymer
Carbon black

1332-86-4

5-10%

3.5g/m

3

3.5g/m

3

Not listed

3.5g/m

3

Iron oxide

1317-61-9

5-10%

Not listed

Not listed

Not listed

Not listed

Polypropylene 9010-79-1

1-5%

Not listed

Not listed

Not listed

Not listed

parafirine

8002-73-2

1-5%

Not listed

Not listed

Not listed

Not listed

Most Important Hazards and Effects of the Products
Human  Health  Effects  : There are no anticipated carcinogenic effects from exposur based on animal tests

performed using toner. When used as intented according to instructions, studies
do not indicate any symptons fibrosis will occur.

Environmental Effects : No data are available.
Specific hazards :

Dust explosion (like most finely dicided organic powders).

Route(s) of Entry  :

    Yes

 No

Possible but very unusual.

Remove to fresh air. If symptons occur, consult medical personnel.

Skin Contact : Wash with soapand water for 15 minutes or until particle is removed.

If irritation does occur, consult medical personnel.

Eye Contact :

Flush eyes immediately with water for 15 minutes. If irritation does occur, consult
medical personnel.

Ingestion :

Rinse with water and drink several glasses of water. If irritation or discomfort does
occur, consult medical personnel.

DG

B

Date Revised : Aug.7, 2001

Date Issued : Jun.1, 1998

MSDS No. F-00831

:  water, CO

2

, foam and dry chemicals

Special Fire fighting Procedure :  None
Fire and Explosion Hazards

:  Toner material, like most finely divided organic powders, may
   form an explosive mixture.

:

None

Environmental Precautions :

None

:

Wipe off with paper or cloth. Do not use vacuum cleaner when a large
amount is released. It, like finely divided organic powders, is capable
of creating dust explosion.

Handling
Technical Measures

: None

Precautions

: None

Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or

during long term exposure, as with any non-toxic dust. Try not to disperse the
particles.

Storage
Technical measures

: None

Storage  Conditions

: Keep container closed and Store in a cool and dry place.

Keep out of the reach of children.

Incompatible Products : None

Engineering Measures
Ventilation

: Not required under intended use.

Exposure limit values
OSHA-PEL(USA)

: 15g/m

3

 (Total Dust), 5g/m

3

 (Respirable Dust)

ACGIH-TLV(USA)

: 10g/m

3

 (Total Dust), 3g/m

3

 (Respirable Dust)

Personal Protective Equipment
Respiratory Protection

: Not required under intended use.

Hand Protection

: Not required under intended use.

Eye Protection

: Not required under intended use.

Skin Protection

: Not required under intended use.

Other  Protective  equipment : Use of a dust mask and goggles are recommended when handling a

large quantity of toner or during long term exposure, as with any non-
toxic dust.

Appearance

Physical State :

  Solid Form : Powder

Color : Black

Oder  :  Odorless

: Not applicable

: Not applicable

: No data

: Not applicable

Ignition Point (°C)

: No data

: No data

: 1.1 (bulk density : 0.34)

: Negligible

DG

B

Date Revised : Aug.7, 2001

Date Issued : Jun.1, 1998

MSDS No. F-00831

:Stable

:Dust explosion, like most finely divided organic powders.

: Electri discharge, throwing into fire.

: Oxidizing Materials

Hazardous Decomposition Products : Co, CO

2

 and NO

x

: None

Ingestion (oral) : LD50 > 2000mg/kg (Rats)
Dermal

: LD 50 > 2000mg/kg (rats

Inhalation

: No  data

Eye irritation

: Not an irritant

Skin irritation

: Not an irritant

Skin sensitizer : No  sensitization

: Negative (Ames Test)

: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible

human carcinogen).  This classification is given to chemicals for which there is inade-
quate human evidence, but sufficient animal evidence on which to base an opinion
of carcinogenicity.  The classification is based upon the development of lung tumors
in rats receiving chronic inhalation exposures to free carbon black at levels that induce
particle overload of the lung.  Studies performed in animal models other than rats
did not show any association between carbon black and lung tumors.
Moreover, a two-year cancer bioassay using a typical toner preparation containing
carbon black demonstrated no association between toner exposure and tumor
development in rats.

: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate

degree of lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m

3

)

exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the
animals in the middle (4mg/m

3

) exposure group, but no pulmonary change was

reported in the lowest (1mg/m

3

) exposure group, the most relevant level to potential

human exposures.

No data are available.

:Waste material may be dumped or incinerated under conditions which meet

all federal, state and local environmental regulations.

Contaminated Packaging : Waste may be disposed or incinerated under conditions which meet all

federal, state and local environmental regulations.

DG

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Date Revised : Aug.7, 2001

Date Issued : Jun.1, 1998

MSDS No. F-00831

:None

:None

 IMDG

: None

: None

TSCA (Toxic Substances Control Act)

:

    All chemical substances in this product comply with all applicable rules or order under TSCA.
SARA (Superfund Amendments and Reauthorization Act) Title III
    302 Extreme Hazardous Substance

:  None

    311/312 Hazard Classification

:  None

EU Information
       1999/45/EEC and 67/548/EEC
       Symbol & Indication

: Not required

  R-Phrase

:  Not  required

  76/769/EEC

: All chemical substances in this product comply with all
  applicable rules or order under 76/69/EEC.

NFPA  Rating  (USA)

: Health = 1

Flammability = 1   Reactivity = 0

WHMIS Legislation (Canada)

: This product is not a controlled product.

IARC (1998) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.

65, Printing Process And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp-
149-261 H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper,
J. C. MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pul-
monary  Response to Toner upon Chronic Inhalation Exposure in Rats.  Fundamental
and Applied Toxicology 17, pp. 280-299.

The information of this data sheet represents our current data and best opinion as to the proper use in
handling of this product under normal conditions. However, all materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we do not guarantee that these
are the only hazards which exist.