Sharp AR-155 (serv.man23) User Manual / Operation Manual ▷ View online
S H A R P
Date Issued:Aug. 1, 1999
MATERIAL SAFETY DATA SHEET
MSDS No. F-00971
Section 1.
Product Identification
Product:
AR-150TD/TD-J/DC/MI/MI-J/LI/CI/MT/MT-J/LT/CT (Black Toner)
AR-150TD/TD-J/DC/MI/MI-J/LI/CI/MT/MT-J/LT/CT (Black Toner)
Section 2.
Supplier’s Name and Address
Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
(Country)
(Name and Telephone Number)
U.S.A.
Sharp Electronics Corporation
Telephone number for information: 1-800-237-4277
Emergency telephone number:
Telephone number for information: 1-800-237-4277
Emergency telephone number:
1-800-255-3924
Canada
Sharp Electronics of Canada Ltd.
Telephone number for information: 905-890-2100
Emergency telephone number:
Emergency telephone number:
1-800-255-3924
United Kingdom
Sharp Electronics (U.K.) Ltd.
Telephone number for information: 01923-474013
Telephone number for information: 01923-474013
Section 3.
Ingredients
Ingredients
CAS No.
Proportion
OSHA PEL ACGIH TLV Other Limits
Styrene-Acrylate copolymer
29497-14-1
> 88 %
Not listed
Not listed
None
Carbon black
1333-86-4
< 6.0%
3.5m
g
/m
3
3.5m
g
/m
3
None
Iron oxide
1309-38-2
< 4.5%
Not listed
Not listed
None
Metal Complex dye
109125-51-1
< 1.5%
0.5m
g
/m
3
0.5m
g
/m
3
None
109125-50-0
84179-66-8
Section 4.
Hazardous Identification (Emergency Overview)
Toner is a fine, black powder possessing no immediate hazard. There are no anticipated carcinogenic
effects from exposure based on animal tests performed using toner. When used as intended according
to instructions, studies do not indicate any symptoms of fibrosis will occur.
effects from exposure based on animal tests performed using toner. When used as intended according
to instructions, studies do not indicate any symptoms of fibrosis will occur.
Section 5.
Health Hazard Data
Route(s) of Entry:
Inhalation?
Skin?
Ingestion?
Yes
No
Possible but very unusual.
Health Hazards:
Acute oral toxicity ------------- LDL0 of this toner is over 2,000m
g
/k
g
.
Mutagenicity -------------------- The result of Ames test is negative.
Carcinogenicity: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classification is given to chemicals for which there is
inadequate human evidence, but sufficient animal evidence on which to base an
opinion of carcinogenicity. The classification is based upon the development of lung
tumors in rats receiving chronic inhalation exposures to free carbon black at levels
that induce particle overload of the lung. Studies performed in animal models other
than rats did not show any association between carbon black and lung tumors.
Moreover, a two-year cancer bioassay using a typical toner preparation containing
carbon black demonstrated no association between toner exposure and tumor
development in rats.
inadequate human evidence, but sufficient animal evidence on which to base an
opinion of carcinogenicity. The classification is based upon the development of lung
tumors in rats receiving chronic inhalation exposures to free carbon black at levels
that induce particle overload of the lung. Studies performed in animal models other
than rats did not show any association between carbon black and lung tumors.
Moreover, a two-year cancer bioassay using a typical toner preparation containing
carbon black demonstrated no association between toner exposure and tumor
development in rats.
Chronic Effect:
In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate
degree of lung fibrosis was observed in 92% of the rats in the high concentration
(16m
degree of lung fibrosis was observed in 92% of the rats in the high concentration
(16m
g
/m
3
) exposure group, and a minimal to mild degree of fibrosis was noted in
22% of the animals in the middle (4m
g
/m
3
) exposure group, but no pulmonary change
was reported in the lowest (1m
g
/m
3
) exposure group, the most relevant level to
potential human exposures.
Signs and Symptoms of Exposure: Minimal irritation to respiratory tract may occur as with exposure
to any non-toxic dust.
Medical Conditions Generally Aggravated by Exposure: None
Emergency and First Aid Procedures:
Emergency and First Aid Procedures:
Inhalation;
Remove to fresh air. If effects occur, consult medical personnel.
Eye;
In case of contact, immediately flush eyes with water for 15 minutes.
{
Section 6.
Physical Chemical Characteristics
Boiling / Melting Point: Not applicable
Specific Gravity:
1.1
Vapor Pressure:
Not applicable
Solubility in Water: Negligible
Vapor Density:
Not applicable
PH:
Not applicable
Evaporation Rate:
Not applicable
Viscosity:
Not applicable
Appearance:
Fine powder
Color:
Black
Odor:
Odorless
Section 7.
Fire and Explosion Data
Flash Point (Method Used):
Not applicable
Ignition Temperature:
>350°C
Flammable Limits:
(LEL); Not applicable
(UEL); Not applicable
Extinguishing Media:
CO
2
, dry chemical, foam or water
Special Fire Fighting Procedure:
None
Unusual Fire and Explosion Hazard: This material has no unusual fire or explosion hazards.
Sensitivity to Mechanical Impact:
Sensitivity to Mechanical Impact:
None
Sensitivity to Static Charge:
None
Section 8.
Reactivity Data
Stability:
Stable
Incompatibility (Material to Avoid):
None
Hazardous Decomposition:
CO and NOx
Hazardous Polymerization:
Will not occur.
Section 9.
Precautions for Safe Handling and Use
Personal Protection Information (Respiratory, Eye Protection and Protective Glove):
Use of a dust mask is recommended when handling a large quantity of toner or
during long term exposure, as with any non-toxic dust.
during long term exposure, as with any non-toxic dust.
Engineering Control / Ventilation:
Not required.
Work / Hygienic Practice:
Inhalation should be minimized as with any non-toxic
dust.
dust.
Steps to be taken in case of Spill or Leak: Sweep up or clean up with vacuum cleaner.
Waste Disposal Method:
Waste Disposal Method:
Waste material may be dumped or incinerated under
conditions which meet all federal, state and local
environmental regulations.
conditions which meet all federal, state and local
environmental regulations.
Section 10.
Regulatory Information
NFPA Rating (U.S.A.):
Health = 1
Flammability = 1
Reactivity = 0
WHMIS Legislation (Canada):
This product is not a controlled product.
Transport Information:
This product is not a hazardous material.
UN No.:
None allocated.
Section 11.
Other Information
References: IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals
to Humans, Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro
Compounds, Lyon, pp-149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C.
MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary
Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied
Toxicology 17, pp. 280-299
Compounds, Lyon, pp-149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C.
MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary
Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied
Toxicology 17, pp. 280-299
S H A R P
Date Issued :Aug. 1, 1999
MATERIAL SAFETY DATA SHEET
MSDS No. F-30971
Section 1.
Product Identification
Product
AR-150TD/TD-J/DC/MI/MI-J/LI/CI (Black Developer)
AR-150TD/TD-J/DC/MI/MI-J/LI/CI (Black Developer)
Section 2.
Supplier’s Name and Address
Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
(Country)
(Name and Telephone Number)
U.S.A.
Sharp Electronics Corporation
Telephone number for information: 1-800-237-4277
Emergency telephone number:
Telephone number for information: 1-800-237-4277
Emergency telephone number:
1-800-255-3924
Canada
Sharp Electronics of Canada Ltd.
Telephone number for information: 905-890-2100
Emergency telephone number:
Emergency telephone number:
1-800-255-3924
United Kingdom
Sharp Electronics (U.K.) Ltd.
Telephone number for information: 01923-474013
Telephone number for information: 01923-474013
Section 3.
Ingredients
Ingredients
CAS No.
Proportion
OSHA PEL ACGIH TLV Other Limits
Iron powder
7439-89-6
> 92.5%
Not listed
Not listed
None
Styrene-Acrylate copolymer
29497-14-1
< 7.0%
Not listed
Not listed
None
Carbon black
1333-86-4
< 0.5%
3.5m
g
/m
3
3.5m
g
/m
3
None
Section 4.
Hazardous Identification (Emergency Overview)
Developer is a black powder containing small amounts of toner, and possessing no immediate hazard.
There are no anticipated carcinogenic effects from exposure based on animal tests performed using
toner.
There are no anticipated carcinogenic effects from exposure based on animal tests performed using
toner.
Section 5.
Health Hazard Data
Route(s) of Entry:
Inhalation?
Skin?
Ingestion?
No
No
Possible but very unusual.
Health Hazards:
Acute oral toxicity ------------- LDL0 of this toner which is included in this developer
is over 2,000m
g
/k
g
.
Mutagenicity -------------------- The toner, which is included in this developer, has been
tested on Ames test. The result is negative.
Carcinogenicity: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classification is given to chemicals for which there is
inadequate human evidence, but sufficient animal evidence on which to base an
opinion of carcinogenicity. The classification is based upon the development of lung
tumors in rats receiving chronic inhalation exposures to free carbon black at levels
that induce particle overload of the lung. Studies performed in animal models other
than rats did not show any association between carbon black and lung tumors.
While there have been no studies to date using developer, a two-year cancer
bioassay using a typical toner preparation containing carbon black (a small amount
of toner is included in the developer mixture) demonstrated no association between
toner exposure and tumor development in rats.
inadequate human evidence, but sufficient animal evidence on which to base an
opinion of carcinogenicity. The classification is based upon the development of lung
tumors in rats receiving chronic inhalation exposures to free carbon black at levels
that induce particle overload of the lung. Studies performed in animal models other
than rats did not show any association between carbon black and lung tumors.
While there have been no studies to date using developer, a two-year cancer
bioassay using a typical toner preparation containing carbon black (a small amount
of toner is included in the developer mixture) demonstrated no association between
toner exposure and tumor development in rats.
Signs and Symptoms of Exposure: Minimal irritation to respiratory tract may occur as with exposure
to any non-toxic dust.
Medical Conditions Generally Aggravated by Exposure: None
Emergency and First Aid Procedures:
Emergency and First Aid Procedures:
Inhalation;
Remove to fresh air. If effects occur, consult medical personnel.
Eye;
In case of contact, immediately flush eyes with water for 15 minutes.
Section 6.
Physical Chemical Characteristics
Boiling / Melting Point: Not applicable
Specific Gravity:
about 7.3
Vapor Pressure:
Not applicable
Solubility in Water: Negligible
Vapor Density:
Not applicable
PH:
Not applicable
Evaporation Rate:
Not applicable
Viscosity:
Not applicable
Appearance:
Fine powder
Color:
Black
Odor:
Odorless
Section 7.
Fire and Explosion Data
Flash Point (Method Used):
Not applicable
Ignition Temperature:
>350°C
Flammable Limits:
(LEL); Not applicable
(UEL); Not applicable
Extinguishing Media:
CO
2
, dry chemical, foam or water
Special Fire Fighting Procedure:
None
Unusual Fire and Explosion Hazard: This material has no unusual fire or explosion hazards.
Sensitivity to Mechanical Impact:
Sensitivity to Mechanical Impact:
None
Sensitivity to Static Charge:
None
Section 8.
Reactivity Data
Stability:
Stable
Incompatibility (Material to Avoid):
None
Hazardous Decomposition:
CO and NOx
Hazardous Polymerization:
Will not occur.
Section 9.
Precautions for Safe Handling and Use
Personal Protection Information (Respiratory, Eye Protection and Protective Glove):
None required under normal use.
Engineering Control / Ventilation:
Not required.
Work / Hygienic Practice:
Not required.
Steps to be taken in case of Spill or Leak:
Sweep up or clean up with vacuum cleaner.
Waste Disposal Method:
Waste material may be dumped or incinerated under
conditions which meet all federal, state and local
environmental regulations.
conditions which meet all federal, state and local
environmental regulations.
Section 10.
Regulatory Information
NFPA Rating (U.S.A.):
Health = 1
Flammability = 1
Reactivity = 0
WHMIS Legislation (Canada):
This product is not a controlled product.
Transport Information:
This product is not a hazardous material.
UN No.:
None allocated.
Section 11.
Other Information
References: IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals
to Humans, Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro
Compounds, Lyon, pp-149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C.
MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary
Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied
Toxicology 17, pp. 280-299
Compounds, Lyon, pp-149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C.
MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary
Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied
Toxicology 17, pp. 280-299
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