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Document Systems Support

45

Page:2/3

Date Issued :May 29. 2001

                                                                                                                                  Date Revised:Mar. 1. 2001

MSDS NO. F-31011

Personal Precautions           :  None
Environmental Precautions  :  None
Methods for Cleaning Up      :  Wipe off with paper or cloth.  DO not use vacuum cleaner when a large amount is released.

It, like most finely divided organic powders, is capable of creating

                                                   a  dust explosion.

Technical Measures    : None
Precautions                 : None

      Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or during long term

exposure, as with any non-toxic dust. Try not to disperse the particles.

   Storage
     Technical Measures    : None
     Storage Conditions      : Keep container closed and Store in a cool and dry place.

Keep out of the reach of children.

     Incompatible Products : None

       Ventilation                           : None required with intended use.

       OSHA-PEL(USA)                : 15mg/m3 (Total Dust) , 5mg/m3 (Respirable Dust)

     ACGIH-TLV(USA)              :  10mg/m3(Total Dust) , 3mg/m3 (Respirable Dust)

      Respiratory Protection         :  None required when used as intended in Sharp equipment.
      Hand Protection                  :  None required when used as intended in Sharp equipment.
      Eye Protection                     :  None required when used as intended in Sharp equipment.
      Skin Protection                    :  None required when used as intended in Sharp equipment.
      Other Protective equipment  :  Use of a dust mask and goggles are recommended when handling a large quantity of toner or

during long term exposure, as with any non-toxic dust.

       Physical State : Solid             Form: Powder                Color: Black             Odor: odorless

Ph                                          :  Not applicable
Boiling/Melting Point            :  Not applicable
Flash Point (

C)                     :  Not applicable

Explosion Properties             :  No data
Density(g/cm³)                      :  6   (bulk density : 2.35)
Solubility in water                :  Negligible

Stability                                               :  Stable
Hazardous Reactions                            :   Dust explosion, like most finely divided organic powders.
Conditions to avoid                               :   Electric discharge, throwing into fire.
Materials to avoid                                 :   Oxidizing Materials
Hazardous Decomposition Products      :   CO, CO2 and NOX
Further Information                               :   None

    Acute Toxicity
          Ingestion(oral)  : LDL

0

>2000mg/kg(Rats)

          Dermal              : No Data
          Inhalation          : No Data
          Eye irritation     : Not an irritant(Rabbits)
          Skin irritation    : Not an irritant(Rabbits)
          Skin sensitizer  : No Data

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Date Issued :May 29. 2001

                                                                                                                              

 Date Revised:Mar. 1. 2001

MSDS NO. F-31011

Mutagenicity         : Negative(Ames Test)

Carcinogenicity    :In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human carcinogen).

This classification is given to chemicals for which there is inadequate human evidence, but
sufficient animal evidence on which to base an opinion of carcinogenicity.  The classification is
based upon the development of lung tumors in rats receiving chronic inhalation exposures to free
carbon black at levels that induce particle overload of the lung.  Studies performed in animal
models other than rats did not show any association between carbon black and lung tumors.
Moreover, a two-year cancer bioassay using a typical toner preparation containing carbon black
demonstrated no association between toner exposure and tumor development in rats.

Chronic Effect      : In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of lung

fibrosis was observed in 92% of the rats in the high concentration (16mg/m

3

) exposure group, and a

minimal to mild degree of fibrosis was noted in22% of the animals in the middle (4mg/m

3

) exposure

group, but no pulmonary change was reported in the lowest (1mg/m

3

) exposure group, the most

relevant level to potential human exposures.

    No data are available.

Waste from residues       : Waste material may be dumped or incinerated under conditions  which meet all federal, state and

local environmental regulations.

    Contaminated Packaging : Waste may be disposed or incinerated under conditions which meet all federal, state and local

environmental regulations.

     UN Classification                    : None
     Land                     DOT(USA) : None
     Sea                      IMDG         : None
     Air                        ICAO-TI     : None

US Information

      TSCA(Toxic Substances Control Act)  :
           All chemical substances in this product comply with all applicable rules or order under TSCA.
      SARA(Superfund Amendments and Reauthorization Act) Title III
           302 Extreme Hazardous Substance: None
           311/312 Hazard Classification         : None
    EU Information
      1999/45/EC and 67/548/EEC
           Symbol & Indication                         :  Not required
           R-Phrase                                          :  Not required
      76/769/EEC :  All chemical substances in this product comply with all applicable rules or order under 76/769/EEC.

NFPA  Rating(USA)                 : Health=1   Flammability=1   Reactivity=0
WHMIS Legistlation (Canada) : This product is not a controlled product.

    References
        IARC(1996) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65, Printing

Process  And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp.149-261

        H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr,

S.Takenaka, and R.Mermelstein(1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats.
Fundamental and Applied Toxicology 17, pp.280-299.

The information on this data sheet represents our current data and best opinion as to the proper use in handling of this
product under normal conditions.  However, all materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we do not guarantee that these are the only hazards which exist.  

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Date Issued : Nov. 30. 2000

Date Revised:

                                                                                                                    

MSDS NO.: F-01011

Product Name :               AR-450NT/ST/T  (Black Toner)

       Supplier Identification :     Sharp Corporation

22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

Local suppliers are listed below.  Please contact the nearest supplier for additional information.

(Country)

(Name  and  Telephone  Number)

U.S.A.

Sharp Electronics Corporation

Telephone number for information:  1-800-237-4277

Emergency telephone number  : 1-800-255-3924

Canada

Sharp Electronics of Canada Ltd.
Telephone number for information :    905-890-2100
Emergency telephone number :        1-800-255-3924

United

Kingdom

Sharp Electronics (U. K.) Ltd.
Telephone number for information :    01923-47-4013

Australia

Sharp Corporation of Australia PTY. Ltd.:
Telephone number for information: 1300-13-50-22

Germany

Sharp Electronics (Europe) GMBH
Telephone number for information :    40-2376-2737

Polyester resin           

213077-22-6

80-90%

Not listed

Not listed

Not listed

Not listed

Carbon black

1333-86-4

<5%

3.5mg/m

3

3.5mg/m

3

Not listed

3mg/m

3

Iron oxide

1309-38-2

<3%

Not listed

Not listed

Not listed

Not listed

Metal Complex dye

109125-51-1

<2%

0.5mg/m

3

0.5mg/m

3

Not listed

Not listed

109125-50-0

84179-66-8

Polypropylene

9003-07-0

<2%

Not listed

Not listed

Not listed

Not listed

Most Important Hazards and Effects of the Products

       Human Health Effects : There are no anticipated carcinogenic effects from exposure based on animal tests performed using

toner.  When used as intended according to instructions, studies do not indicate any
symptoms of fibrosis will occur.

       Environmental Effects :  No data are available.

Specific hazards :  Dust explosion (like most finely divided organic powders)

 

    Yes

 No

Possible but very unusual.

Inhalation      : Remove to fresh air.  If symptoms occur, consult medical personnel.
Skin Contact  :  Wash with soap  and water for 15 minutes or until particle is removed.
                        If irritation does occur, consult medical personnel.
Eye Contact   :  flush eyes immediately with water for 15 minutes. If irritation does occur, consult medical personnel.
Ingestion       : Rinse with water and drink several glasses of water . If irritation or discomfort does occur, consult medical

personnel.

Extinguishing Media :  water , CO2, foam and dry chemicals
Special Fire fighting Procedures :  None
Fire and Explosion Hazards : Toner material, like most finely divided organic powders, may form

 

an explosive

 

mixture.

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Date Issued : Nov. 30. 2000

Date Revised:

                                                                                                                    

MSDS NO.: F-01011

Personal Precautions          :  None
Environmental Precautions : None
Methods for Cleaning Up :   Wipe off with paper or cloth.  DO not use vacuum cleaner when a large amount is

                                              released.  It, like most finely divided organic powders, is capable of creating a  dust explosion.

Technical Measures : None

      Precautions             : None
      Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or during long term

exposure, as with any non-toxic dust.   Try not to disperse the particles.

  Storage
     Technical Measures : None
     Storage Conditions  : Keep container closed and Store in a cool and dry place.
                                      Keep out of the reach of children.
     Incompatible Products : None

       Ventilation : None required with intended use.

       OSHA-PEL(USA) : 15mg/m3 (Total Dust) , 5mg/m3 (Respirable Dust)
       ACGIH-TLV(USA): 10mg/m3(Total Dust) , 3mg/m3 (Respirable Dust)

      Respiratory Protection :  None required when used as intended in Sharp equipment.
      Hand Protection          :  None required when used as intended in Sharp equipment.
      Eye Protection             :  None required when used as intended in Sharp equipment.
      Skin Protection            :  None required when used as intended in Sharp equipment.
      Other Protective equipment :  Use of a dust mask and goggles are recommended when handling a large quantity of toner or

during long term exposure, as with any non-toxic dust.

       Physical State : Solid             Form: Powder                Color: Black             Odor: odorless

Ph :                                             Not applicable
Boiling/Melting Point :              Not applicable
Softening Point (

C):                100-130

C):                       Not applicable

C):                    >350

Explosion Properties :              No data
Density(g/cm³) :                        1.1                 (bulk density : 0.4)
Solubility in water :                   Negligible

Stability :   Stable
Hazardous Reactions:  Dust explosion, like most finely divided organic powders.
Conditions to avoid :  Electric discharge, throwing into fire.
Materials to avoid :  Oxidizing Materials
Hazardous Decomposition Products :  CO, CO2 and NOX
Further Information :  None

      Acute Toxicity

Ingestion(oral)  : LDL

0

>2000mg/kg(Rats)

Dermal             : No Data

          Inhalation         : No Data
          Eye irritation     : Not an irritant(Rabbits)
          Skin irritation   : Not an irritant(Rabbits)
          Skin sensitizer  : No Data
     Mutagenicity          : Negative(Ames Test