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Model
DM-2000 (serv.man13)
Pages
28
Size
487.6 KB
Type
PDF
Document
User Manual / Operation Manual
Brand
Device
Copying Equipment / DM2000-Operation Manual Part4
File
dm-2000-sm13.pdf
Date

Sharp DM-2000 (serv.man13) User Manual / Operation Manual ▷ View online

75
S H A R P
 Date Issued:Nov. 1, 1998
MATERIAL SAFETY DATA SHEET
MSDS No. F-00841
Section 1.
Product Identification
Product:
AR-200DC/AR-200LT (Black Toner)
Section 2.
Supplier’s Name and Address
Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
(Country)
(Name and Telephone Number)
U.S.A.
Sharp Electronics Corporation
Telephone number for information: 1-800-237-4277
Emergency telephone number:
1-800-255-3924
Canada
Sharp Electronics of Canada Ltd.
Telephone number for information: 905-890-2100
Emergency telephone number:
1-800-255-3924
United Kingdom
Sharp Electronics (U.K.) Ltd.
Telephone number for information: 01923-474013
Section 3.
Ingredients
Ingredients
CAS No.
Proportion
OSHA PEL
ACGIH TLV
Other Limits
Styrene-Acrylate copolymer
29497-14-1
> 88 %
Not listed
Not listed
None
Carbon black
1333-86-4
< 6.0%
3.5m
g
/m
3
3.5m
g
/m
3
None
Iron oxide
1309-38-2
< 4.5%
Not listed
Not listed
None
Metal Complex dye
109125-51-1
< 1.5%
0.5m
g
/m
3
0.5m
g
/m
3
None
109125-50-0
84179-66-8
Section 4.
Hazardous Identification (Emergency Overview)
Toner is a fine, black powder possessing no immediate hazard. There are no anticipated carcinogenic effects
from exposure based on animal tests performed using toner. When used as intended according to instructions,
studies do not indicate any symptoms of fibrosis will occur.
Section 5.
Health Hazard Data
Route(s) of Entry:
Inhalation?
Skin?
Ingestion?
Yes
No
Possible but very unusual.
Health Hazards:
Acute oral toxicity ------- LDL
0
 of this toner is over 2,000m
g
/k
g
.
Mutagenicity -------------- The result of Ames test is negative.
Carcinogenicity: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human
carcinogen). This classification is given to chemicals for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies
performed in animal models other than rats did not show any association between carbon
black and lung tumors.  Moreover, a two-year cancer bioassay using a typical toner preparation
containing carbon black demonstrated no association between toner exposure and tumor
development in rats.
Chronic Effect:
In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree
of lung fibrosis was observed in 92% of the rats in the high concentration (16m
g
/m
3
) exposure
group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle
(4m
g
/m
3
) exposure group, but no pulmonary change was reported in the lowest (1m
g
/m
3
)
exposure group, the most relevant level to potential human exposures.
Signs and Symptoms of Exposure:
Minimal irritation to respiratory tract may occur as with exposure to any
non-toxic dust.
Medical Conditions Generally Aggravated by Exposure: None
Emergency and First Aid Procedures:
Inhalation; Remove to fresh air. If effects occur, consult medical personnel.
Eye;
In case of contact, immediately flush eyes with water for 15 minutes.
76
Section 6.
Physical Chemical Characteristics
Boiling / Melting Point: Not applicable
Specific Gravity:
1.1
Vapor Pressure:
Not applicable
Solubility in Water: Negligible
Vapor Density:
Not applicable
PH:
Not applicable
Evaporation Rate:
Not applicable
Viscosity:
Not applicable
Appearance:
Fine powder
Color:
Black
Odor:
Odorless
Section 7.
Fire and Explosion Data
Flash Point (Method Used):
Not applicable
Ignition Temperature:
>350
°
C
Flammable Limits:
(LEL); Not applicable
(UEL); Not applicable
Extinguishing Media:
CO
2
, dry chemical, foam or water
Special Fire Fighting Procedure:
None
Unusual Fire and Explosion Hazard: This material has no unusual fire or explosion hazards.
Sensitivity to Mechanical Impact:
None
Sensitivity to Static Charge:
None
Section 8.
Reactivity Data
Stability:
Stable
Incompatibility (Material to Avoid):
None
Hazardous Decomposition:
CO and NOx
Hazardous Polymerization:
Will not occur.
Section 9.
Precautions for Safe Handling and Use
Personal Protection Information (Respiratory, Eye Protection and Protective Glove):
Use of a dust mask is recommended when handling a large quantity of toner or during long
term exposure, as with any non-toxic dust.
Engineering Control / Ventilation:
Not required.
Work / Hygienic Practice:
Inhalation should be minimized as with any non-toxic dust.
Steps to be taken in case of Spill or Leak: Sweep up or clean up with vacuum cleaner.
Waste Disposal Method:
Waste material may be dumped or incinerated under conditions
which meet all federal, state and local environmental regulations.
Section 10. Regulatory Information
NFPA Rating (U.S.A.):
Health = 1
Flammability = 1
Reactivity = 0
WHMIS Legislation (Canada):
This product is not a controlled product.
Transport Information:
This product is not a hazardous material.
UN No.:
None allocated.
Section 11. Other Information
References: IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro Compounds, Lyon, pp-
149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. MacKenzie,
P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary Response to Toner upon
Chronic Inhalation Exposure in Rats.  Fundamental and Applied Toxicology 17, pp. 280-299
77
S H A R P
Date Issued :Nov. 1, 1998
MATERIAL SAFETY DATA SHEET
MSDS No. F-30841
Section 1.
Product Identification
Product
AR-200DC/AR-200LD(Black Developer)
Section 2.
Supplier’s
Name and Address
Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
(Country)
(Name and Telephone Number)
U.S.A.
Sharp Electronics Corporation
Telephone number for information: 1-800-237-4277
Emergency telephone number:
1-800-255-3924
Canada
Sharp Electronics of Canada Ltd.
Telephone number for information: 905-890-2100
Emergency telephone number:
1-800-255-3924
United Kingdom
Sharp Electronics (U.K.) Ltd.
Telephone number for information: 01923-474013
Section 3.
Ingredients
Ingredients
CAS No.
Proportion
OSHA PEL
ACGIH TLV
Other Limits
Iron powder
7439-89-6
> 92.5%
Not listed
Not listed
None
Styrene-Acrylate copolymer
29497-14-1
< 7.0%
Not listed
Not listed
None
Carbon black
1333-86-4
< 0.5%
3.5m
g
/m
3
3.5m
g
/m
3
None
Section 4.
Hazardous Identification (Emergency Overview)
Developer is a black powder containing small amounts of toner, and possessing no immediate hazard.
There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner.
Section 5.
Health Hazard Data
Route(s) of Entry:
Inhalation?
Skin?
Ingestion?
No
No
Possible but very unusual.
Health Hazards:
Acute oral toxicity ----------- LDL
0
 of this toner which is included in this developer is over
2,000m
g
/k
g
.
Mutagenicity ------------------ The toner, which is included in this developer, has been tested on
Ames test. The result is negative.
Carcinogenicity: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human
carcinogen). This classification is given to chemicals for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies
performed in animal models other than rats did not show any association between carbon
black and lung tumors.
While there have been no studies to date using developer, a two-year cancer bioassay using
a typical toner preparation containing carbon black (a small amount of toner is included in the
developer mixture) demonstrated no association between toner exposure and tumor
development in rats.
Signs and Symptoms of Exposure:
Minimal irritation to respiratory tract may occur as with exposure to any
non-toxic dust.
Medical Conditions Generally Aggravated by Exposure:
None
Emergency and First Aid Procedures:
Inhalation; Remove to fresh air.  If effects occur, consult medical personnel.
Eye;
In case of contact, immediately flush eyes with water for 15 minutes.
78
Section 6.
Physical Chemical Characteristics
Boiling / Melting Point: Not applicable
Specific Gravity:
about 7.3
Vapor Pressure:
Not applicable
Solubility in Water: Negligible
Vapor Density:
Not applicable
PH:
Not applicable
Evaporation Rate:
Not applicable
Viscosity:
Not applicable
Appearance:
Fine powder
Color:
Black
Odor:
Odorless
Section 7.
Fire and Explosion Data
Flash Point (Method Used):
Not applicable
Ignition Temperature:
>350
°
C
Flammable Limits:
(LEL); Not applicable
(UEL); Not applicable
Extinguishing Media:
CO
2
, dry chemical, foam or water
Special Fire Fighting Procedure:
None
Unusual Fire and Explosion Hazard: This material has no unusual fire or explosion hazards.
Sensitivity to Mechanical Impact:
None
Sensitivity to Static Charge:
None
Section 8.
Reactivity Data
Stability:
Stable
Incompatibility (Material to Avoid):
None
Hazardous Decomposition:
CO and NOx
Hazardous Polymerization:
Will not occur.
Section 9.
Precautions for Safe Handling and Use
Personal Protection Information (Respiratory, Eye Protection and Protective Glove):
None required under normal use.
Engineering Control / Ventilation:
Not required.
Work / Hygienic Practice:
Not required.
Steps to be taken in case of Spill or Leak: Sweep up or clean up with vacuum cleaner.
Waste Disposal Method:
Waste material may be dumped or incinerated under conditions
which meet all federal, state and local environmental regulations.
Section 10. Regulatory Information
NFPA Rating (U.S.A.):
Health = 1
Flammability = 1
Reactivity = 0
WHMIS Legislation (Canada):
This product is not a controlled product.
Transport Information:
This product is not a hazardous material.
UN No.:
None allocated.
Section 11. Other Information
References: IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro Compounds, Lyon, pp-
149-261
H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. MacKenzie,
P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary Response to Toner upon
Chronic Inhalation Exposure in Rats. Fundamental and Applied Toxicology 17, pp. 280-299
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