AR-M316 (serv.man88). Material Safety Data Sheet for AR-310T toner — Sharp Copying Equipment Regulatory Data (repair manual)

Model
AR-M316 (serv.man88)
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4 Few pages! See other manuals at the bottom of the first or last page.
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PDF
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Regulatory Data
Brand
Device
Copying Equipment / Material Safety Data Sheet for AR-310T toner
File
ar-m316-sm88.pdf
Date

View Sharp AR-M316 (serv.man88) Regulatory Data online

 
MATERIAL  SAFETY  DATA  SHEET                          
Page : 1/4 
  
 
Date Issued   : Feb. 1, 2007 
MSDS No. F-01481 
 
  1.PRODUCT AND COMPANY IDENTIFICATION 
Product Name 
:    AR-310NT/ AR-310T/ AR-310ST/ AR-310FT/ AR-310ST-C/ AR-311ST-C 
(Black Toner) 
Supplier Identification  : Sharp Corporation 
 
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan 
Local suppliers are listed below.  Please contact the nearest supplier for additional information.
 
Area 
(Country) 
(Name  and  Telephone  Number) 
U.S.A. 
Sharp Electronics Corporation 
Sharp Plaza, Mahwah, NJ 
Telephone number for information 
: 1-800-237-4277 
Emergency telephone number 
: 1-800-255-3924 
North 
America 
Canada 
Sharp Electronics of Canada Ltd. 
Telephone number for information 
: 905-890-2100 
Emergency telephone number 
: 1-800-255-3924 
Oceania 
Australia 
Sharp Corporation of Australia PTY. Ltd. 
No1 Huntingwood Drive Huntingwood Blacktown N.S.W. 
Telephone number for information 
: 1300-13-50-22 
Germany 
Sharp Electronics (Europe) GMBH 
Sonninstrasse 3, 20097 Hamburg 
Telephone number to access MSDS 
: 040-2376-2185 
For more information 
: 040-2376-2613 
United 
Kingdom 
Sharp Electronics (U. K.) Ltd. 
Telephone number for information 
: 08705-274-277 
France 
Sharp Electronics France S.A. 
Telephone number for information 
: 01-49-90-34-00 
Austria 
Sharp Electronics GMBH 
Telephone number for information 
: 01-727-19-0 
Italy 
Sharp Electronics (Italy) S.P.A. 
Telephone number for information 
: 02895951 
Spain 
Sharp Electronics (Espana) S.A. 
Telephone number for information 
: 93-581-97-00 
Netherlands 
Sharp Electronics Benelux B.V. 
Telephone number for information 
: 30-6359500 
Sweden 
Sharp Electronics Nordic AB 
Telephone number for information 
: 08-634-36-00 
Europe 
Switzerland Sharp 
Electronics(Schweiz)AG 
Telephone number for information 
: 01-846-6111 
Middle 
East 
U.A.E. 
Sharp Middle East FZE 
P.O.Box 17115 Jebel Ali, Dubai 
Telephone number for information 
: 04-815311 
  
 
  
  2.COMPOSITION / INFORMATION ON INGREDIENTS 
Substance[  ]             Preparation[X] 
     Ingredient CAS 
No. Proportion
OSHA PEL ACGIH 
TLV MAK-TWA NOHSC-TWA 
Styrene-Acrylate 
copolymer        
Carbon black 
Iron oxide 
Metal Complex dye
* 
29497-14-1 
 
1333-86-4 
1309-38-2 
109125-51-1 
84179-66-8 
     85-95%
 
      5-10%
        1-5%
       <  2%
Not listed 
 
3.5mg/m
3
 
Not listed 
0.5mg/m
3
 
Not listed 
 
3.5mg/m
3
 
Not listed 
0.5mg/m
3
 
Not listed 
 
Not listed 
Not listed 
Not listed 
Not listed 
 
3mg/m
3
 
Not listed 
Not listed 
 * EC N0. : 400-110-2, Symbol letter : F,N , R Phrase : R11, R50/53 
 
 
MATERIAL  SAFETY  DATA  SHEET                          
Page : 2/4 
  
 
Date Issued   : Feb. 1, 2007 
MSDS No. F-01481 
 
  3.HAZARDS IDENTIFICATION 
Most Important Hazards and Effects of the Products 
Human Health Effects  : There are no anticipated carcinogenic effects from exposure based on animal tests 
performed using toner. When used as intended according to instructions, studies do not 
indicate any symptoms of fibrosis will occur. 
Environmental Effects  : not toxic to aquatic organisms 
Specific Hazards 
: Dust explosion (like most finely divided organic powders) 
Directive 1999/45/EC(Europe)  : Not classified as dangerous 
  
  4.FIRST-AID MEASURES 
Route(s) of Entry :  Inhalation?  
Skin? 
  Ingestion? 
 
Yes 
No 
Possible but very unusual. 
  
Inhalation : Remove to fresh air. If symptoms occur, consult medical personnel.
 
Skin Contact  : Wash with soap and water for 15 minutes or until particle is removed. 
If irritation does occur, consult medical personnel. 
Eye Contact : Flush eyes immediately with water for 15 minutes. If irritation does occur, consult medical personnel.
 
Ingestion : Rinse with water and drink several glasses of water. If irritation or discomfort does occur, consult 
medical personnel. 
  
  5.FIRE-FIGHTING MEASURES 
Extinguishing Media 
: Water, CO
2
, foam and dry chemicals 
Special Fire Fighting Procedures  : None 
Fire and Explosion Hazards 
: Toner material, like most finely divided organic powders, may form an explosive 
mixture. 
  
  6.ACCIDENTAL RELEASE MEASURES 
Personal Precautions 
: None 
Environmental Precautions 
: None 
Methods for Cleaning Up 
: Wipe off with paper or cloth. Do not use vacuum cleaner when a large amount is 
released. It, like most finely divided organic powders, is capable of creating a 
dust explosion. 
 
  7.HANDLING AND STORAGE 
Handling 
Technical Measures 
: None 
Precautions : 
None 
Safe Handling Advice  : Use of a dust mask is recommended when handling a large quantity of toner or during long 
term exposure, as with any non-toxic dust. Try not to disperse the particles. 
Storage 
Technical Measures 
: None 
Storage Conditions 
: Keep container closed and Store in a cool and dry place. 
Keep out of the reach of children. 
Incompatible Products  : None  
  8.EXPOSURE CONTROLS / PERSONAL PROTECTION 
Engineering Measures 
Ventilation 
: Not required under intended use. 
 
MATERIAL  SAFETY  DATA  SHEET                          
Page : 3/4 
  
 
Date Issued   : Feb. 1, 2007 
MSDS No. F-01481 
 
Exposure Limit Values 
OSHA-PEL(USA) : 
15mg/m
3
 (Total Dust),  5mg/m
3
 (Respirable Dust) 
ACGIH-TLV(USA) : 
10mg/m
3
 (Total Dust),  3mg/m
3
 (Respirable Dust)
 
Personal Protective Equipment 
Respiratory Protection 
: Not required under intended use. 
Hand Protection 
: Not required under intended use. 
Eye Protection 
: Not required under intended use. 
Skin Protection 
: Not required under intended use.
 
Other Protective Equipment 
: Use of a dust mask and goggles are recommended when handling a large 
quantity of toner or during long term exposure, as with any non-toxic dust. 
  
  9.PHYSICAL AND CHEMICAL PROPERTIES 
Appearance 
Physical State : Solid 
Form : Powder 
Color : Black 
Odor : odorless 
Ph : Not applicable 
Boiling / Melting Point 
: Not applicable 
Softening Point(°C) 
: 100 - 130 
Flash Point(°C) 
: Not applicable 
lgnition Point(°C ) 
: > 350 
Explosion Properties 
: No data 
Density(g/cm³) : 1.1   (bulk density : 0.35) 
Solubility in Water 
: Negligible  
 
10.STABILITY AND REACTIVITY 
Stability : Stable 
Hazardous Reactions 
: Dust explosion, like most finely divided organic powders. 
Conditions to Avoid 
: Electric discharge, throwing into fire. 
Materials to Avoid 
: Oxidizing Materials 
Hazardous Decomposition Products  : CO, CO
2
 and NO
X
 
Further Information 
: None  
  
11.TOXICOLOGICAL INFORMATION 
Acute Toxicity 
Ingestion(oral) : 
LD
50
 > 2500mg/kg (Rats) 
Inhalation 
: No data 
Eye irritation 
: Not an irritant (Rabbits) 
Skin irritation 
: Not an irritant (Rabbits) 
Skin sensitizer 
: No sensitization 
Mutagenicity : Negative (Ames Test) 
Carcinogenicity : In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human 
carcinogen). This classification is given to chemicals for which there is inadequate human 
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The 
classification is based upon the development of lung tumors in rats receiving chronic inhalation 
exposures to free carbon black at levels that induce particle overload of the lung. Studies 
performed in animal models other than rats did not show any association between carbon black 
and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation 
containing carbon black demonstrated no association between toner exposure and tumor 
development in rats. 
 
MATERIAL  SAFETY  DATA  SHEET                          
Page : 4/4 
  
 
Date Issued   : Feb. 1, 2007 
MSDS No. F-01481 
 
Chronic Effect 
: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of 
lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m
3
) exposure 
group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle 
(4mg/m
3
) exposure group, but no pulmonary change was reported in the lowest (1mg/m
3
exposure group, the most relevant level to potential human exposures. 
  
12.ECOLOGICAL INFORMATION 
Ecotoxicity :  On available data, toner is not harmful to aquatic organisms 
  
13.DISPOSAL CONSIDERATIONS 
Waste from Residues 
: Waste material may be dumped or incinerated under conditions  which meet all federal, 
state and local environmental regulations. 
Contaminated Packaging  : Waste may be disposed or incinerated under conditions which meet all federal, state 
and local environmental regulations. 
  
14.TRANSPORT INFORMATION 
UN Classification 
: None 
Not classified as hazardous for transport.  
15.REGULATORY INFORMATION 
US Information 
TSCA(Toxic Substances Control Act)  : 
All chemical substances in this product comply with all applicable rules or order under TSCA. 
SARA(Superfund Amendments and Reauthorization Act) Title III 
302 Extreme Hazardous Substance : None 
311/312 Hazard Classification 
: None 
EU Information 
1999/45/EC and 67/548/EEC 
Symbol & Indication 
: Not required 
R-Phrase 
: Not required 
76/769/EEC 
: All chemical substances in this product comply with all applicable rules or 
order under 76/769/EEC.  
16.OTHER INFORMATION 
NFPA Rating (USA) 
: Health=1 
Flammability=1 Reactivity=0 
WHMIS Legislation (Canada)  : This product is not a controlled product. 
List of R phrases 
: R11 : Highly flammable  
                                                    R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in 
                                                                    the  aquatic environment. 
References 
IARC(1996) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65, 
Printing Process  And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp.149-261  
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr, 
S.Takenaka, and R.Mermelstein(1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats. 
Fundamental and Applied Toxicology 17, pp.280-299.  
The information on this data sheet represents our current data and best opinion as to the proper use in handling of this 
product under normal conditions. However, all materials may present unknown hazards and should be used with 
caution. Although certain hazards are described herein, we do not guarantee that these are the only hazards which 
exist. 
 
MATERIAL  SAFETY  DATA  SHEET                          
Page : 4/4 
  
 
Date Issued   : Feb. 1, 2007 
MSDS No. F-01481 
 
Chronic Effect 
: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of 
lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m
3
) exposure 
group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle 
(4mg/m
3
) exposure group, but no pulmonary change was reported in the lowest (1mg/m
3
exposure group, the most relevant level to potential human exposures. 
  
12.ECOLOGICAL INFORMATION 
Ecotoxicity :  On available data, toner is not harmful to aquatic organisms 
  
13.DISPOSAL CONSIDERATIONS 
Waste from Residues 
: Waste material may be dumped or incinerated under conditions  which meet all federal, 
state and local environmental regulations. 
Contaminated Packaging  : Waste may be disposed or incinerated under conditions which meet all federal, state 
and local environmental regulations. 
  
14.TRANSPORT INFORMATION 
UN Classification 
: None 
Not classified as hazardous for transport.  
15.REGULATORY INFORMATION 
US Information 
TSCA(Toxic Substances Control Act)  : 
All chemical substances in this product comply with all applicable rules or order under TSCA. 
SARA(Superfund Amendments and Reauthorization Act) Title III 
302 Extreme Hazardous Substance : None 
311/312 Hazard Classification 
: None 
EU Information 
1999/45/EC and 67/548/EEC 
Symbol & Indication 
: Not required 
R-Phrase 
: Not required 
76/769/EEC 
: All chemical substances in this product comply with all applicable rules or 
order under 76/769/EEC.  
16.OTHER INFORMATION 
NFPA Rating (USA) 
: Health=1 
Flammability=1 Reactivity=0 
WHMIS Legislation (Canada)  : This product is not a controlled product. 
List of R phrases 
: R11 : Highly flammable  
                                                    R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in 
                                                                    the  aquatic environment. 
References 
IARC(1996) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65, 
Printing Process  And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp.149-261  
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr, 
S.Takenaka, and R.Mermelstein(1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats. 
Fundamental and Applied Toxicology 17, pp.280-299.  
The information on this data sheet represents our current data and best opinion as to the proper use in handling of this 
product under normal conditions. However, all materials may present unknown hazards and should be used with 
caution. Although certain hazards are described herein, we do not guarantee that these are the only hazards which 
exist. 

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